The simplest answer would be
--Setup a test table called "t1"
create table t1 (date datetime, value int)
-- Load the data. -- Note: date format different than in the question
insert into t1 Select '5/18/2010 13:00',40 union all Select '5/18/2010 14:00',20 union all Select '5/18/2010 15:00',60 union all Select '5/18/2010 16:00',30 union all Select '5/18/2010 17:00',60 union all Select '5/18/2010 18:00',25
-- find the row with the max qty and min date.
select * from t1 where value = (select max(value) from t1) and date = (select min(date) from t1 where value = (select max(value) from t1))
I know you can do the "TOP 1" answer, but usually your solution gets just complicated enough that you can't use that for some reason.