The easiest "quick and dirty" way of determining the frequency is to simply measure the time distance of the first and last maximum (or minimum) that you can reliably determine and divide by the number of periods in between.
I did this and it looks like it's ringing mostly at 2 MHz.
A more precise method would be to cut out a segment (as you already have done) and do an FFT on it. Determine the peak frequency. For these type of events a rectangular window should be fine. You can zero pad to increase frequency resolution.
It would help if you have some idea of the physical system that is creating the response. It looks like a 2nd order lowpass filter with pretty high Q. If that's a good assumption, you can try to do a parametric fit of the curve. Below is a starting point

However, the damping behavior is not monoton, as shown in the following figure.
I think you are misinterpreting what's happening here. This looks very much like a system reacting to noise spikes. Each spike triggers the impulse response of the system which would indeed be decreasing monotonically (mostly).
What you see here is most likely a double spike, i.e. two events that partially overlap. The overlap is a tricky to deal with, so if you have enough "single" events, I would discard the "doubles".