Two possible answers.
a) TexForm converts a Mathematica expression into something you can use to paste it in TeX:
TeXForm[x/Sqrt[5]] ==> \frac{x}{\sqrt{5}} A usually more convenient way of achieving this is right-clicking output, and selecting Copy as | LaTeX.
b) If all you're looking for is a neater display form inside Mathematica, then have a look at MatrixForm and TraditionalForm.
m = {{1, 2}, {3, 4}}; TraditionalForm[m] MatrixForm[m] 
Be careful only to use these commands to display already existing values. For example, when you're writing something like
m = TraditionalForm[{{1, 2}, {3, 4}}]; Eigenvalues[m] then m is not assigned the matrix, but its TraditionalForm representation, which does not behave like a matrix anymore. The output of the above is simply a silly line:

TexFormconverts a Mathematica expression into something you can use to paste it in TeX:TeXForm[x/Sqrt[5]] ==> \frac{x}{\sqrt{5}}A usually more convenient way of achieving this is right-clicking output, and selecting
Copy as | LaTeX.If all you're looking for is a neater display form inside Mathematica, then have a look at
MatrixFormandTraditionalForm.m = {{1, 2}, {3, 4}}; TraditionalForm[m] MatrixForm[m]
Be careful only to use these commands to display already existing values. For example, when you're writing something like
m = TraditionalForm[{{1, 2}, {3, 4}}]; Eigenvalues[m]then
mis not assigned the matrix, but itsTraditionalFormrepresentation, which does not behave like a matrix anymore. The output of the above is simply a silly line: