LikedBy is a multi valued lookup column. You have to $expand it in the query. Just make GET request to the following end-point, in response you will get LikesCount and LikedBy
/_api/web/lists/GetByTitle('List Name')/Items?$select=LikesCount,LikedBy/Title&$expand=LikedBy
Above query will give you the Title of LikedBy user as I am using LikedBy/Title in $select like following
{ "d": { "results": [ { "__metadata": { "id": "f2592d31-7960-42c1-a51b-b0cbf6238483", "uri": "https://xxx.sharepoint.com/_api/Web/Lists(guid'ba8a6814-61cd-4dc6-92f2-ae088316744a')/Items(1)", "etag": "\"2\"", "type": "SP.Data.Short_x0020_DescriptionListItem" }, "LikedBy": { "results": [ { "__metadata": { "id": "e81c95c7-b0f0-44ff-aa46-71d6a7782bc8", "type": "SP.Data.UserInfoItem" }, "Title": "Mohammad Mazumder" } ] }, "LikesCount": 1 } ] } }
If you need more fields of LikedBy user, then mention them in the $select like following.
$select=LikesCount,LikedBy/Id,LikedBy/Title&$expand=LikedBy
If you have time, have a look on this article.