You say that you "noticed that industry participants generally responded more negatively compared to the other two groups.". And you seem concerned that this introduces a "baseline difference". But the baseline is exactly what you are measuring, and that differencdifference is exactly what you want to find (if it exists).
If you had measured these perceived career barriers before, and then after some intervention, you would be concerned about a prior (baseline) bias in one groiupgroup, if your goal was to measure the effect of the intervention. But you gave no indication of such an intervention. So all your data can measure is the baseline.
So the fact that industry participants are more negative in their views is what you should find. And when you think aboputabout it, it is intuitively reasonable. Students have no idea (yet) what a "real job" will look like, and thus are probably a bit too optimistic. Career faculty will never have any such idea (academia is not at all like corporate/industry work). And industry participants have some personal experience with this, and probably have a bit more of a sober perspective. Believe me, as a 40+ years industry participant, industry/corporate work can often be a real pain in the ... If it were not for the $$, many people would be in a different profession, or would switch employer more often.
Now, wrt exactly which test to use? You have 3 groups, so KWt would be a natural choice. But it is an omnibus test, so all it will tell you is that 1 sample is stochastically superior to another one, but will not tell you which they are; you will need to run post-hoc 2 sample tests to find this out. Moreover, KWt suffers from the Behrens-Fisher problem (inflated Type I errors, or seriously reduced power, when variances/sample sizes are not equal). Last, stochastic superiority is a non transitive property (i.e. you can observe "rock/paper/scissors" situations were sample A is stochastically superior to B, which is superior to C, but then C is superior to A). INIn such cases KWt will lose almost all power (excellent paper on this situation). So I am not a big fan of KWt; too many caveats.