I want to show that as dimension of a matrix increases, the condition number generally tends to increase too.
There's not really a way to formalize this because it's not really true. My answer will have two parts:
- Using diagonal matrices, I show that your desired statement is not really true.
- I show why there is some formalization that might help if you think about "growing dimension" more precisely as nested principal minors.
Diagonal Matrices
It's possible to construct sequences of matrices where the dimension grows and the behavior of the condition number can be arbitrary: it can increase, decrease, or remain constant. The simplest case to study this is diagonal matrices with positive entries, i.e. $$ D = \begin{bmatrix} d_1 & & \\ & \ddots & \\ & & d_n \end{bmatrix} \enspace, $$ where $d_1, \dots d_n > 0$. Recall that the eigenvalues of $D$ are its diagonal entries $d_1, \dots d_n$ and that for symmetric matrices, the condition number is the ratio of the largest and smallest eigenvalues. In other words, the condition number of $D$ is $\kappa(D) = d_{\max} / d_{\min} \geq 1$. The condition number of the diagonal matrix doesn't depend on its dimension (which is $n$) but rather the ratio of its largest and smallest eigenvalues. Only by changing $d_1 \dots d_n$ (and not really the dimension $n$) do we change the condition number. This example shows how it's possible to construct sequences of matrices where the dimension grows and the behavior of the condition number can be arbitrary (I'm happy to elaborate on this if it's not clear).
Nested Principal Minors
On the other hand, there is some sense in which your statement can be made formal when you replace "increasing dimension" with "nested principle minors". The simplest example of a principle minor is the $k$-by-$k$ submatrix that corresponds to taking the first $1 \dots k$ rows and columns. But let me add that I would not interpret this next statement as generally meaning that "condition number increases with dimension". The proof uses Cauchy Interlacing Theorem.
Theorem: Let $A$ be an $n$-by-$n$ symmetric positive definite matrix. Let $A_1 \dots A_n$ be a sequence of nested principal minors of $A$. Then, the condition number satisfies the inequalities $\kappa(A_1) \leq \cdots \leq \kappa(A_n)$.
Proof: Let $A'$ be an $m$-by-$m$ principal minor of $A$, where $m \leq n$. Without loss of generality, it suffices to show that $\kappa(A') \leq \kappa(A)$. Let $0 < \lambda_1 \leq \dots \leq \lambda_n$ be eigenvalues of $A$ and let $0 < \lambda'_1 \leq \dots \leq \lambda'_m$ be the eigenvalues of $A'$. By Cauchy Interlacing theorem, $\lambda_1 \leq \lambda_1'$ and $\lambda'_m \leq \lambda_n$. Thus, the condition number satisfies the inequality $$ \kappa(A') = \frac{\lambda_m'}{\lambda_1'} \leq \frac{\lambda_n}{\lambda_1} = \kappa(A) \enspace. \blacksquare $$