For periodic refresh you must use NEXT clause. To refresh everyday at 00:00:
ALTER MATERIALIZED VIEW EMPLOYEE_INFO REFRESH COMPLETE NEXT TRUNC(SYSDATE) + 1
To refresh every 6 hours:
ALTER MATERIALIZED VIEW EMPLOYEE_INFO REFRESH COMPLETE NEXT SYSDATE + 6/24
From documentation (ALTER MATERIALIZED VIEW):
START WITH Clause
Specify START WITH date to indicate a date for the first automatic refresh time.
NEXT Clause
Specify NEXT to indicate a date expression for calculating the interval between automatic refreshes.
Both the START WITH and NEXT values must evaluate to a time in the future. If you omit the START WITH value, then Oracle Database determines the first automatic refresh time by evaluating the NEXT expression with respect to the creation time of the materialized view. If you specify a START WITH value but omit the NEXT value, then Oracle Database refreshes the materialized view only once. If you omit both the START WITH and NEXT values, or if you omit the alter_mv_refresh entirely, then Oracle Database does not automatically refresh the materialized view.
At the time of the next automatic refresh, Oracle Database refreshes the materialized view, evaluates the NEXT expression to determine the next automatic refresh time, and continues to refresh automatically.