I was thinking to convert to cartesian coordinates and then find when the slope of the tangent line is $1$, but I get a messy equation $2\cos^2\theta -2\sin^2\theta=4\sin^2\theta\cos\theta$ I was wondering if there was an easy way as it is hard to get values from this.
Edit: The equation ends up simplifying to $\tan(2\theta) = 1$, but for future reference is this the best method?