The sum is a little strange, because the multinomial coefficient makes sense only when $k_1+k_2+\ldots+k_n=m$. I will assume this restriction is (implicitly) intended and that $n$ is fixed. (If not, a variation of the following solution will work.)
Notice that the set
$$\{0 \le k_1 \le k_2 \le \ldots \le k_n \le m\}$$
is in one-to-one correspondence with the $n$ differences
$$(k_1, k_2-k_1, \ldots, k_n - k_{n-1}, m-k_n).$$
The elements of the latter are non-negative integers summing to $m$. If we add $1$ to each, they will be positive and sum (obviously) to $m+n$. The set of such sequences is obtained with IntegerPartitions.
Working backwards, then, we can invoke IntegerPartitions, subtract $1$ from all elements, apply Multinomial, and Sum what we have obtained. This leads to the efficient and straightforward solution:
f[m_Integer, n_Integer] := Sum[Multinomial @@ k, {k, # - ConstantArray[1, n] & /@ IntegerPartitions[m + n, {n}]}]
(Including {n} as an argument to IntegerPartitions causes the number of $k_i$ to be fixed at $n$.)
For example, f[5,4] adds up all such multinomial coefficients having $n=4$ terms summing to $m=5$:
$$\eqalign{ &\sum_{0 \le k_1\le k_2\le k_3\le k_4 \le 5}\binom{5}{k_1\ k_2\ k_3\ k_4} \\ &= \binom{5}{0\ 0\ 0\ 5} + \binom{5}{0\ 0\ 1\ 4} + \binom{5}{0\ 0\ 2\ 3}+ \binom{5}{0\ 1\ 1\ 3}+ \binom{5}{0\ 1\ 2\ 2}+ \binom{5}{1\ 1\ 1\ 2} \\ &= 1 + 5 + 10 + 20 + 30 + 60 \\ & = 126. }$$
Edit
I have speculated (in comments below) that the role of L might be to limit the possible values of the $k_i$ to a set. Specifically, this interpretation asks for the calculation of
$$\sum_{k_i \in L: 0\le k_1\le \ldots \le k_n \le m} \binom{m}{k_1\ k_2\ \ldots\ k_n}$$
where $m$, $n$, and $L$ are given. When $m$ is not too large, a simple way is to modify the preceding solution to include only those index vectors $(k_i)$ whose components lie in $L$:
f[m_Integer, n_Integer, support_List] := With[{indexes = Select[# - ConstantArray[1, n] & /@ IntegerPartitions[m + n, {n}], Complement[#, support] == {} &]}, Reap[Sum[Multinomial @@ Sow[k], {k, indexes}]]]
The inclusion of Sow and Reap (which can readily be removed after testing is complete) provides a method to monitor the calculation: each set of indexes is saved by Sow and all are returned via Reap after the calculation is complete.
Examples
f[5, 4, Range[0, 5]] (* Reproduce the preceding example *)
$\{126,\{\{\{5,0,0,0\},\{4,1,0,0\},\{3,2,0,0\},\{3,1,1,0\},\{2,2,1,0\},\{2,1,1,1\}\}\}\}$
It obtains the same answer of $126$, followed by the detailed list of indexes contributing to that value.
f[8, 4, {1, 2, 4, 5}]
$\{3696,\{\{\{5,1,1,1\},\{4,2,1,1\},\{2,2,2,2\}\}\}\}$
The indexes clearly are limited to the set $\{1,2,4,5\}$ in this calculation. Without that limitation, we would invoke f[8, 4, Range[0,8]], obtaining $8143$ instead of $3696$; $15$ different index vectors contribute to this sum.
f[m_, bigL_]for a start. $\endgroup$Totalare common beginner problems. As forTotalI'm not sure what you intended but either you don't understand what theTotalfunction does or you placed it without thinking. If you want a function that will add up any values that are given to it and then return that total when requested I can show you how. $\endgroup$