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246,667 questions
0 votes
0 answers
4 views
How to calculate transition dipole moment computationally?
Interested to calculate TDM of a molecule in the presence of a dielectric. What is the go-to way right now in research circles?
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0 answers
10 views
Deriving the Boltzmann equation
In classical mechanics, the space of states is the cotangent bundle of configuration space. This space of states is also called phase space. In the physical case where phase space represents all ...
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0 answers
11 views
How to implement constraints via delta functions?
I have a question regarding the implementation of constraint equations as delta functions in integrals. My confusion can best be illustrated with a quick example: Consider a Gaussian integral of the ...
-1 votes
0 answers
19 views
Is quantum channels can be simulated via quantum trajectories? [closed]
Lookin for a way to run quantum circuits with de-polarizing noise via quantum trajectories and not density matrix
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13 views
Why can't we measure non-linear operators in QM using single shot measurements?
Consider an operator like the modular Hamiltonian $K$ defined by $$\rho=e^{-K}$$ where $\rho$ is some (reduced) density matrix. So $K$ depends non-linearly on $\rho$ in general. It can be shown that ...
1 vote
0 answers
16 views
Curious about entropy and information theory in Bohmian mechanics
I've been playing around with Bohmian mechanics in electronic systems. I really like the interpretation of particle trajectories in terms of the continuity, Hamilton Jacobi equation and guiding ...
0 votes
1 answer
56 views
Using conserved quantities as variables in Mechanics
I am currently taking a course in theoretical (classical) Mechanics, where I have learned about the Darboux theorem. My professor has also mentioned one can "reduce the system by symmetry", ...
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47 views
What does it mean that the Ricci scalar is zero? [duplicate]
I was watching this video on how to derive the Schwarzschild metric when at around 4:30, he mentions that because the Ricci scalar $R$ is zero, there is no immediate change in volume due to the ...
-2 votes
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27 views
Motion of Thomsons Jumping Ring [closed]
Hi! For the last few weeks i've been trying to figure out the motion equations for the ring in the Jumping Ring experiment, with little to no success. I know the differential equation that would ...
1 vote
1 answer
26 views
Trouble understanding the boundary conditions for the Blasius boundary layer equation
In Section 7.2.1 of Bergman's Fundamentals of Heat and Mass Transfer, there is a derivation of the Blasius equation $$ 2 \frac{d^3 f}{d \eta^3} + f \frac{d^2 f}{d \eta^2} = 0$$ through the definitions ...
3 votes
3 answers
54 views
Condensation of water droplets on one side of a bottle!
Here is what I observed: Background: I kept this bottle in my room, at a place where: half of it was in complete darkness (well, minimal light did fall on it, but very minimal). the other half ...
-1 votes
2 answers
46 views
Proper times of two inertial observers. [closed]
According to the Lorentz transformations, if an observer $O'$ moves at a relative velocity $\beta$ with respect to another observer $O$, the proper times $t$ and $t'$ would be related by: $$ t=\sqrt{1-...
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1 answer
69 views
How valid is U238-Pb dating?
C14 is created locally and recently, and decays at a fixed half-life much longer than the time taken to be absorbed, so accurate-ish dating by isotope ratio is possible, but dating the Earth with the ...
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15 views
Source recommendation for spin glasses and their relation with SYK model
I want to learn Edwards-Anderson and Sherrington-Kirkpatrick models properly with their calculations (Replica symmetry, phase transition, etc.). I need couple of sources such as books and papers ...
3 votes
1 answer
95 views
Trying to understand Reeh-Schlieder
In an attempt to understand the Reeh-Schlieder theorem, I am currently studying this paper, in which Witten provides a discussion using the formalism of quantum field theory. It is quite ...
-6 votes
0 answers
53 views
Are people aware of this Functional Causal Chain of Momentum (FCCM)? [closed]
I was pondering the nature of momentum conservation in non-ideal systems and noticed a beautiful, continuous functional/mathematical chain linking potential energy all the way to momentum. It frames ...
5 votes
3 answers
598 views
Mathematical rigor behind renormalization
I struggle to understand how theories that are based on renormalization can be considered mathematically rigorous. I understand how renormalization works for non-abelian theories, through loop ...
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26 views
Am I correct in my understanding of how the reverse Carnot Cycle works? [duplicate]
So, when the gas (initially at the heater temperature T1) is compressed isothermally, it does not come into contact with the cooler, and in order to prevent the gas temperature from exceeding the ...
0 votes
1 answer
44 views
Resonant frequency of multi diameter closed pipe
I'm trying to make sense of how resonances in pipes work. I gather that, in the instance below, the fundamental resonant frequency of the 1m closed pipe (ignoring end correction etc.) is $$ f_{0} = \...
-4 votes
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34 views
A metal sphere is suspended in water at 0°c by a thread when water is heated to 4°c , what happens to the tension in the thread? [closed]
A metal sphere is suspended in water at 0°c by a thread when water is heated to 4°c , what happens to the tension in the thread? I thought that the tension would increase because the water would ...
0 votes
0 answers
44 views
Overlap integral in quantum chemistry [closed]
Imagine C has positive formal charge bonded to three methyl groups (CH3). How do we compute the overlap between sigma bond and empty $p$-orbital? The motivation for this is to show how energy ...
-4 votes
1 answer
61 views
Model of hitting a mosquito [closed]
I was thinking how could we model the attempt of hitting a mosquito standing on a wall. The mosquito (a point P) is standing on a wall (a plane) and we are trying to hit it with an object of area A ...
0 votes
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46 views
Why is it said that in the distant future, all objects outside the local group will be forever out of our reach? [duplicate]
I've heard this statement from a few sources and the reasoning given is something the lones of that the expansion of the universe would have made objects too far and red shifted to observe, and reach. ...
1 vote
2 answers
143 views
Why the reverse Carnot Cycle works?
I don't understand why the reverse Carnot Cycle works. Let's consider the isothermal expansion of a gas (body). The gas does work, but its temperature remains constant. For this to happen, the gas ...
3 votes
1 answer
154 views
Ideal gas equation
While deriving ideal gas equation we assumed the container to be a cuboid and then we took the volume to be $lbh$ where l, b, h are length, breadth, and height respectively. Will the equation still be ...
0 votes
0 answers
65 views
Classical mechanics vs quantum mechanics [closed]
In classical mechanics we say that a classical particle obeys the equations of motion, whereas in quantum mechanics a particle can take any path, not just the classical one. But when we quantize a ...
-1 votes
0 answers
65 views
Can a physical quantity be arbitrarily introduced? [duplicate]
Acceleration involves a squared time item, and Newton's law of universal gravitation contains a product of two masses. Such mathematical expressions seem to be meaningless when taken in isolation; ...
1 vote
2 answers
377 views
Invariance of the interval in Schutz - maths error?
Reading Schutz's book on GR: On page 9, there's a derivation that I don't follow. $\newcommand{\d}{\Delta} \newcommand{\b}[1]{\bar{#1}}$ Then in the expression for $\d\b{s}^2$, $$\d\b{s}^2 = -(\d\b{...
2 votes
2 answers
138 views
Callen's Thermodynamics - how can equilibrium states be specified by internal energy?
I am currently reflecting a bit on the formal structure of the theory presented in Callen's classic text Thermodynamics and an Introduction to Thermostatistics. I was originally going to post a more ...
5 votes
5 answers
774 views
How do entangled particles stay correlated if they do not interact with each other at measurement?
I'm having trouble understanding how two entangled particles stay correlated once they are measured. As an example, if they are anti-correlated in their spins, and one particle is measured to have a ...