Because min isn't an option for FormsModule validation. The available validators are required, minlength, maxlength and pattern; an empty input is invalid because you have required. The min attribute prevents the HTML input from decrementing below zero using the arrow keys or the up-down buttons in the input, but isn't used for validation; you could write a custom validator to do this.
Note that there is an issue on GitHub discussing support for the HTML 5 validators; the fact that it's currently closed doesn't bode well for min and max getting included in the near future.