This invocation actually calls the apply method on the companion object to the List class.
Many scala classes have a companion object, which is a singleton object with the same name as the class. Defining methods on this companion object, is the scala equivalent of java's static methods. It is very common for these companion objects to have one or more apply methods that are used as constructor/factory functions to create an instance of the class. In this case the List object has a method that takes a variable number of arguments of the same type, and creates a List of those objects.
In fact, if you define a case class, scala will automatically define a companion object that, among other things, includes and apply method that takes the same arguments as the case class's constructor, which is why you don't need to use new when constructing case classes.
The list instance also has an apply method, which is used to index into the list, but since it is defined on the List class it only applies to instances of the class, not the object List itself.