ClearAll[regF] regF = PolyhedronData["Dodecahedron", "RegionFunction"]; regF[x, y, z] // TeXForm
$\scriptsize\sqrt{10 \left(5+\sqrt{5}\right)} (2 x+z)+5 \left(2+\sqrt{5}\right)\geq 0\land \sqrt{10 \left(5+\sqrt{5}\right)} (2 x+z)\leq 5 \left(2+\sqrt{5}\right)\land \sqrt{50-10 \sqrt{5}} x+\sqrt{10 \left(5+\sqrt{5}\right)} z\leq 5 \left(\left(1+\sqrt{5}\right) y+\sqrt{5}+2\right)\land \sqrt{2 \left(5+\sqrt{5}\right)} z\leq 2+\sqrt{5}\land \sqrt{50-10 \sqrt{5}} x+5 \left(1+\sqrt{5}\right) y+\sqrt{10 \left(5+\sqrt{5}\right)} z\leq 5 \left(2+\sqrt{5}\right)\land 2 \sqrt{5 \left(5+2 \sqrt{5}\right)} x+10 y\leq \sqrt{10 \left(5+\sqrt{5}\right)} z+5 \left(2+\sqrt{5}\right)\land 2 \sqrt{5 \left(5+2 \sqrt{5}\right)} x\leq 10 y+\sqrt{10 \left(5+\sqrt{5}\right)} z+5 \left(2+\sqrt{5}\right)\land 5 \left(1+\sqrt{5}\right) y\leq \sqrt{50-10 \sqrt{5}} x+\sqrt{10 \left(5+\sqrt{5}\right)} z+5 \left(2+\sqrt{5}\right)\land z+\sqrt{\frac{5}{8}+\frac{11}{8 \sqrt{5}}}\geq 0\land \sqrt{50-10 \sqrt{5}} x+5 \left(1+\sqrt{5}\right) y+\sqrt{10 \left(5+\sqrt{5}\right)} z+5 \left(2+\sqrt{5}\right)\geq 0\land \sqrt{10 \left(5+\sqrt{5}\right)} z\leq 2 \sqrt{5 \left(5+2 \sqrt{5}\right)} x+5 \left(2 y+\sqrt{5}+2\right)\land 10 y+\sqrt{10 \left(5+\sqrt{5}\right)} z\leq 2 \sqrt{5 \left(5+2 \sqrt{5}\right)} x+5 \left(2+\sqrt{5}\right)$
ClearAll[rotate, rotatedRegF] rotate[t_, axis : ("xaxis" | "yaxis" | "zaxis") : "xaxis"] := RotationTransform[t, axis /. Thread[{"xaxis", "yaxis", "zaxis"} -> IdentityMatrix[3]]] @* List; rotatedRegF[rf_, t_, axis : ("xaxis" | "yaxis" | "zaxis") : "xaxis"][x_, y_, z_] := rf @@ rotate[t, axis][x, y, z] rotatedRegF[regF, t][x, y, z] // TeXForm
$\scriptsize\sqrt{10 \left(5+\sqrt{5}\right)} (y \sin (t)+z \cos (t)+2 x)+5 \left(2+\sqrt{5}\right)\geq 0\land \sqrt{10 \left(5+\sqrt{5}\right)} (y \sin (t)+z \cos (t)+2 x)\leq 5 \left(2+\sqrt{5}\right)\land \sqrt{10 \left(5+\sqrt{5}\right)} (y \sin (t)+z \cos (t))+\sqrt{50-10 \sqrt{5}} x\leq 5 \left(\left(1+\sqrt{5}\right) (y \cos (t)-z \sin (t))+\sqrt{5}+2\right)\land \sqrt{2 \left(5+\sqrt{5}\right)} (y \sin (t)+z \cos (t))\leq 2+\sqrt{5}\land \sqrt{10 \left(5+\sqrt{5}\right)} (y \sin (t)+z \cos (t))+5 \left(1+\sqrt{5}\right) (y \cos (t)-z \sin (t))+\sqrt{50-10 \sqrt{5}} x\leq 5 \left(2+\sqrt{5}\right)\land 10 (y \cos (t)-z \sin (t))+2 \sqrt{5 \left(5+2 \sqrt{5}\right)} x\leq \sqrt{10 \left(5+\sqrt{5}\right)} (y \sin (t)+z \cos (t))+5 \left(2+\sqrt{5}\right)\land 2 \sqrt{5 \left(5+2 \sqrt{5}\right)} x\leq \sqrt{10 \left(5+\sqrt{5}\right)} (y \sin (t)+z \cos (t))+10 (y \cos (t)-z \sin (t))+5 \left(2+\sqrt{5}\right)\land 5 \left(1+\sqrt{5}\right) (y \cos (t)-z \sin (t))\leq \sqrt{10 \left(5+\sqrt{5}\right)} (y \sin (t)+z \cos (t))+\sqrt{50-10 \sqrt{5}} x+5 \left(2+\sqrt{5}\right)\land y \sin (t)+z \cos (t)+\sqrt{\frac{5}{8}+\frac{11}{8 \sqrt{5}}}\geq 0\land \sqrt{10 \left(5+\sqrt{5}\right)} (y \sin (t)+z \cos (t))+5 \left(1+\sqrt{5}\right) (y \cos (t)-z \sin (t))+\sqrt{50-10 \sqrt{5}} x+5 \left(2+\sqrt{5}\right)\geq 0\land \sqrt{10 \left(5+\sqrt{5}\right)} (y \sin (t)+z \cos (t))\leq 5 \left(2 (y \cos (t)-z \sin (t))+\sqrt{5}+2\right)+2 \sqrt{5 \left(5+2 \sqrt{5}\right)} x\land \sqrt{10 \left(5+\sqrt{5}\right)} (y \sin (t)+z \cos (t))+10 (y \cos (t)-z \sin (t))\leq 2 \sqrt{5 \left(5+2 \sqrt{5}\right)} x+5 \left(2+\sqrt{5}\right)$
rfunctions = {"regF", "rotatedRegF[regF,Pi/2]", "rotatedRegF[regF,Pi/2, \"yaxis\"]", "rotatedRegF[regF,Pi/2, \"zaxis\"]"}; Grid[Partition[Labeled[RegionPlot3D[ToExpression[#][x, y, z], {x, -2, 2}, {y, -2, 2}, {z, -2, 2}, PlotPoints -> 40, ImageSize -> 300, Method -> {"ShrinkWrap" -> True}, Boxed -> False, AxesOrigin -> {0, 0, 0}], #, Top] & /@ rfunctions, 2], Dividers -> All]

Update: For interactive display, rendering the polyhedron once and using GeometricTransformation with desired transformation is faster:
ir = PolyhedronData["Dodecahedron", "ImplicitRegion"]; rp = RegionPlot3D[ir, PlotPoints -> 70]; {xaxis, yaxis, zaxis} = IdentityMatrix[3]; Panel @ Manipulate[Row[Panel[ Graphics3D[{{EdgeForm[], FaceForm[], Cuboid[{-3, -3, -3}, {3, 3, 3}], Red, PointSize[Large], Point[ctr]}, EdgeForm[None], FaceForm[Opacity[.5]], GeometricTransformation[rp[[1]], RotationTransform[t, #]]}, Axes -> True, PlotRange -> {{-3, 3}, {-3, 3}, {-3, 3}}, AxesOrigin -> {0, 0, 0}, Boxed -> False, ImageSize -> 300, PlotLabel -> #]] & /@ {xaxis, yaxis, zaxis}], {{t, 0}, -Pi, Pi}, Paneled -> False]

Anchor rotation at, say, vv = {2, 1, 1}:
vv = {2, 1, 1}; centroid = {0.0000305046, -0.0000984894, -0.0000394806}; Manipulate[Row[Panel[ Graphics3D[{{EdgeForm[], FaceForm[], Cuboid[{-3, -3, -3}, {3, 3, 3}], Red, PointSize[Large], Point[vv]}, Dashed, Thick, Opacity[1, Blue], GeometricTransformation[Line[{centroid, vv}], RotationTransform[t, #, vv]], EdgeForm[None], FaceForm[Opacity[.5]], GeometricTransformation[rp[[1]], RotationTransform[t, #, vv]]}, Axes -> True, PlotRange -> {{-6, 6}, {-6, 6}, {-6, 6}}, AxesOrigin -> {0, 0, 0}, Boxed -> False, ImageSize -> 300, PlotLabel -> #]] & /@ {xaxis, yaxis, zaxis}], {{t, 0}, -Pi, Pi}, Paneled -> False]
