Could anybody explain, how the coordinates in Placed influence each other?
ArrayPlot[RandomInteger[10, {400, 400}], ColorFunction -> "ThermometerColors", PlotLegends -> {Placed[ BarLegend[{"ThermometerColors", {0, 100}}, LabelStyle -> Directive[Black, FontSize -> 12], LegendLabel -> "D33 content in wt%", LegendMarkerSize -> 300], {{.35, -.65}, {-0, -3.}}], Placed[Graphics[{Thickness[0.05], Line[{{0, 25}, {10, 25}}], Text[Style["200 nm", Black, FontSize -> 12], {10/2, 26}]}], {{0, 0}, {-1, 3.}}]}] Which gives: 
EDIT:
I would like to have the black bar on the left hand side and the legend on the right hand side, below the arrayplot. I the alignment should be horizontally, not vertically.




