App Engine has a limit regarding the number of files and the size they can have when deploying a new version, quoting the documentation:
An application is limited to 10,000 uploaded files per version. Each file is limited to a maximum size of 32 megabytes. Additionally, if the total size of all files for all versions exceeds the initial free 1 gigabyte, then there will be a $ 0.026 per GB per month charge.
Since your file shaforms.bin seems to be above this limit, you cannot deploy the version as long as it contains this file.
The solution would be to deploy your application without this file, for example, in the Python Standard runtime you can add the skip_files flag to ignore certain files, in your case you could do it by adding the following lines to the app.yaml configuration file:
skip_files: - /Users/tgb29/Desktop/shaforms2/python-docs-samples/appengine/flexible/storage/shaforms.bin
As well, if you need this file to be served from your application, the best would be to upload it to Google Cloud Storage and serve it from there, by using the Client Libraries.